Lime mortars are more porous and soft compared
to other cement-based systems 19 and can be effectively used as a potential candidate
to repair and rehabilitate heritage structures. The sizes of the pores present
in lime mortar materials used in the current study are widely vary from
>10?m to < 1?m. The shape of the pores, orientation and interconnections
with adjoining pores also widely varied. The most pores are isolated and Some
are interconnected. This may be resulted in widely varied permeability of lime
mortars. The sizes of larger pores vary between
200×50?m and 250×100?m with length and breadth ratio varying between 4 and 2.5.
The linear pores are found along inter-granular boundaries with length and
breadth ratio varies between 5 and 4. The smaller pores less than 10?m are well
rounded. The well-developed globular grains amidst the matrix of saccharoidal
carbonate materials are seen in the crystal form of druses with large volumes
of cavities around these crystals. The matrix is enriched with needles of
fibrous carbonate materials (20×0.5?m); are seen as bundles of radiating
aggregates (10?m from the centre to 20?m in peripheral portions) in some
samples. The nature and form of these minerals indicate that they are composed
with significant amount of water, hydroxides or other anionic components. The
chloride crystals are rapidly developed by the process of evaporation of
droplets from their peripheral portions by leaving hallow spaces at their
centre. These hopper or skeletal crystals of sodium chloride enriched halite
were started crystallization initially at the peripheral portions; indicating
that they were rapidly crystallized by evaporation process leaving a hollow
space at the centre. The sizes of hollow spaces present at the centre of these
crystals vary from 0.1×0.1?m to 2×1?m. The peripheral rims of halite vary
between 0.2 to 0.5?m. The sizes of halite crystals vary between 1.5×1.0?m and
0.5?m. A linear chain of such halite crystals indicate that they were
crystallized along a linear crack of 5×2?m; tapering at both ends and appear to
be a flake like fracture at interstitial spaces of the matrix of carbonate
minerals of host; by capillary influx of pore fluid and subsequent evaporation.
However, the matrix and co-existing minerals are characteristically of
non-chlorides and are carbonates. A larger cavity of 4×3?m size is completely
filled with numerous skeletal crystals of halite with cavities at their centre
as aggregates. The successive individual layers of halite are also seen in this
cavity. Some globular beads of halite are also seen within the cavity. The size
of halite also varies from 0.2?m cubes to prisms of 4?m ×0.75?m with length and
breadth ratio exceeding over 5 indicating its rapid free growth in a cavernous
environment. Generally capillary forces
are effective between the pore sizes of 1 and 10?m 19. The EDS analyses
showed that the matrix was essentially composed of carbonate materials.